Solid angle in the spherical polar co-ordinate system:
In spherical polar co-ordinate system, there are three area elements {dA}_r,\ {dA}_{\theta} and {dA}_{\phi} , out of which only the area element {dA}_r subtends a solid angle at the centre O .
[To know about the three types of area elements (CLICK HERE)]

The area element {dA}_r is perpendicular to the direction of the radial vector \vec{r}, Hence only the area {dA}_r subtends a solid angle at the centre O of the sphere.
[To know in detail, why only the area element {dA}_r subtends a solid angle at the centre (CLICK HERE)]
We know that the value of this area element {dA}_r is given by,
{dA}_r=r^2\ \sin\theta\ d\theta\ d\phi .
So the solid angle subtended by the area {dA}_r is given by,
d\omega=\displaystyle{\frac{ r^2\ \sin\theta\ d\theta\ d\phi }{r^2}}= \sin\theta\ d\theta\ d\phi